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Sodium hypoiodite

From Wikipedia, the free encyclopedia
Sodium hypoiodite
Names
IUPAC name
Sodium hypoiodite
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/IO.Na/c1-2;/q-1;+1
    Key: SAFWHKYSCUAGHQ-UHFFFAOYSA-N
  • [O-]I.[Na+]
Properties
INaO
Molar mass 165.893 g·mol−1
Related compounds
Other anions
Other cations
Silver hypoiodite
Related compounds
Hypoiodous acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Sodium hypoiodite is an inorganic chemical used as an oxidant in various organic chemical reactions. It causes iodination of nitrogen atoms, such 1H-benzotriazole to give 1-iodo-1H-benzotriazole and an imine to give the analogous iodoimine.[1] It oxidatively cleaves methyl ketones to give iodoform.[2]

References

[edit]
  1. Kambe, N., ed. (2008). "Product Class 4: Acyclic Dialkyl Sulfoxides and Derivatives". Category 5, Compounds with One Saturated Carbon Heteroatom Bond. doi:10.1055/sos-SD-039-00359. ISBN 978-3-13-118921-9.
  2. Gatenbeck, S.; Bentley, R. (1965). "Naphthaquinone Biosynthesis in Moulds: The Mechanism for Formation of Javanicin". Biochemical Journal. 94 (2): 478–481. doi:10.1042/bj0940478. PMC 1206531. PMID 14348208.