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Nitrosomethane

From Wikipedia, the free encyclopedia
Nitrosomethane
Names
IUPAC name
Nitrosomethane
Identifiers
3D model (JSmol)
  • CN=O
Properties
CH3NO
Molar mass 45.041 g·mol−1
Boiling point −18.3 °C (−0.9 °F; 254.8 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Nitrosomethane is an organic chemical compound with the chemical formula CH3NO.[1]

Chemical properties

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It is an organic chemical compound made up from a methyl group (-CH3) and nitroso group (-NO). At room temperature, it is a flammable gas that boils at -18.3 °C (±9.0 °C).[2]

Synthesis

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Same as trifluoronitrosomethane (a rather rare example of a blue gas), it can be synthesized by the reaction of nitric oxide with methyl iodide with a catalytic amount of mercury metal:

2 CH3I + 2 NO → 2 CH3NO + I2
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Nitrosomethane is related to a few other compounds, such as:

References

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  1. National Center for Biotechnology Information (2026). PubChem Compound Summary for CID 70075, Nitrosomethane. Retrieved March 6, 2026 from https://pubchem.ncbi.nlm.nih.gov/compound/Nitrosomethane.
  2. CSID:63264, https://www.chemspider.com/Chemical-Structure.63264.html, (accessed 16:05, Mar 6, 2026)