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Transition temperature

From Wikipedia, the free encyclopedia

In crystallography, the transition temperature is the temperature at which a material changes from one crystal state (allotrope) to another.[1] More formally, it is the temperature at which two crystalline forms of a substance can co-exist in equilibrium. For example, when rhombic sulfur is heated above 95.6 °C, it changes form into monoclinic sulfur; when cooled below 95.6 °C, it reverts to rhombic sulfur. At 95.6 °C the two forms can co-exist. Another example is tin, which transitions from a cubic crystal below 13.2 °C to a tetragonal crystal above that temperature.[2]

In the case of ferroelectric or ferromagnetic crystals, a transition temperature may be known as the Curie temperature.


See also

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References

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  1. Daintith, John (2008). "allotropy". A Dictionary of Chemistry (6th ed.). Oxford University Press. ISBN 9780199204632.
  2. "Chemical and Physical Information", Toxicological Profile for Tin and Tin Compounds, Agency for Toxic Substances and Disease Registry (US), August 2005, retrieved 2026-03-23