Edge Rewrite
// HTMLRewriter · presentation

This page was redesigned at the edge.

Cloudflare fetched the original article and streamed it through HTMLRewriter to apply an entirely new visual system without rebuilding the source page.

// request.cf · coarse context

A page that knows where it met you.

Only coarse request metadata is shown. This demo does not display or persist visitor IP addresses.

Country
US
Cloudflare location
CMH
Connection
HTTP/2
Language
Not provided

Ray ID: a2328f662ff9d806

Jump to content

Talk:Psymberin

Page contents not supported in other languages.
Add topic
From Wikipedia, the free encyclopedia
Latest comment: 11 years ago by Harmonslide in topic Structural accuracy

Structural accuracy

[edit]

I've seen several references that suggest that the structure needs revising to match http://www.chemspider.com/Chemical-Structure.9867673.html (note that this differs by having a free OH at carbon 15) eg. the graphical abstract: http://pubs.acs.org/doi/ipdf/10.1021/jo400260m

This is indeed correct. Carbon15 should bear a hydroxyl, not a methoxy. Unfortunately, the ChemSpider entry displays the incorrect structure, as does the PubChem entry. This also makes the molecular weight inaccurate. The corresponding CAS entry in SciFinder is correct. Harmonslide (talk) 17:07, 13 July 2015 (UTC)Reply
I've updated the structure with the correct one and will be filling out the Chembox.Harmonslide (talk) 17:29, 13 July 2015 (UTC)Reply
Issues have been addressed. Harmonslide (talk) 19:05, 13 July 2015 (UTC)Reply

Reference issues

[edit]

The 2004 reference was for a ChemInform abstract rather than the primary citation and was thus misleading--it's been corrected to reflect the actual citation. Harmonslide (talk) 17:07, 13 July 2015 (UTC)Reply

The two citation formats have been made consistent with each other. Harmonslide (talk) 17:07, 13 July 2015 (UTC)Reply