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Talk:Dimethyldioxirane

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Latest comment: 16 years ago by 86.32.127.47 in topic Stability

How this differs from acetone peroxide monomer? -Yyy (talk) 10:35, 25 June 2008 (UTC)Reply


Stability

[edit]

We've produced about 6 Liters of DMDO/Acetone. Concentration about 0,045M , i don't think you get the concentration of 0,15 M wich is mentioned in the text at normal way. Literature[1] says about 0,05-0,10 M . And after about 6 months (the solution was stored at about -15 °C) the Concentration was about 0,042 M. In fact the stability isn't as bad as described in this article. 86.32.127.47 (talk) 18:35, 3 April 2010 (UTC)Reply

[1]W. Adam, Y. Y. Chan, D. Cremer, J. Gauss, D. Scheutzow and M. Schindler. Spectral and chemical properties of dimethyldioxirane as determined by experiment and ab initio calculations. Journal of Organic Chemistry, 1987, 52(13):2800-2803 —Preceding unsigned comment added by 86.32.127.47 (talk) 18:37, 3 April 2010 (UTC)Reply

References

  1. W. Adam, Y. Y. Chan, D. Cremer, J. Gauss, D. Scheutzow and M. Schindler. Spectral and chemical properties of dimethyldioxirane as determined by experiment and ab initio calculations. Journal of Organic Chemistry, 1987, 52(13):2800-2803