Talk:Benzylamine

Nice but so what?

This article is about benzyl amine. I removed this essay on the Schotten-Baumann reaction: ", an exemplar of the [[Schotten–Baumann reaction]]<ref>{{cite book|last = Li|first = J. J.|title = Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications|year = 2014|chapter = Schotten–Baumann reaction|publisher = [[Springer Science+Business Media|Springer]]|isbn = 9783319039794|pages = 362|edition = 5th|chapter-url = https://books.google.com/books?id=6mZJ3084ouAC&q=Schotten%E2%80%93Baumann&pg=PA362}}</ref> first described in the 1880s.<ref>{{cite journal|doi = 10.1002/cber.188401702178|title = Ueber die Oxydation des Piperidins|year = 1884|last = Schotten|first = C.|author-link = Carl Schotten|journal = [[Ber. Dtsch. Chem. Ges.]]|volume = 17|issue = 2|pages = 2544–2547|url = https://zenodo.org/record/1425345|language = de}}</ref><ref>{{cite journal|title = Ueber eine einfache Methode der Darstellung von Benzoësäureäthern|year = 1886|last = Baumann|first = E.|author-link = Eugen Baumann|journal = [[Ber. Dtsch. Chem. Ges.]]|doi = 10.1002/cber.188601902348|volume = 19|issue = 2|pages = 3218–3222|url = https://zenodo.org/record/1425451}}</ref> The reaction takes place in a two-phase solvent system (here [[water]] and [[diethyl ether]]) so that the [[hydrogen chloride]] by-product is sequestered in the aqueous phase (and sometimes neutralised with a dissolved base) and thus prevented from protonating the amine and impeding the progress of the reaction. These conditions are often called Schotten-Baumann reaction conditions and are applicable more generally.<ref>{{cite book|chapter-url = https://books.google.com/books?id=AfSFwiNNekQC&q=Schotten%E2%80%93Baumann+reaction+conditions&pg=PA171|pages = 121–168|chapter = 5. Solvent Selection|title =Practical Process Research and Development – A guide for Organic Chemists|first = N. G.|last = Anderson|edition = 2nd|publisher = [[Academic Press]]|year = 2012|isbn = 9780123865380}}</ref> This particular example is useful as a model for the mechanism of [[interfacial polymerisation]] of a diamine with a diacid chloride.<ref>{{cite book|last = Odian|first = G.|title = Principles of Polymerization|year = 2004|publisher = [[John Wiley & Sons]]|chapter = 2.8c – Interfacial Polymerization|isbn = 9780471274001|chapter-url = https://books.google.com/books?id=GbLrBgAAQBAJ&q=Principles+of+Polymerization+odian&pg=PA755|pages = 90–92|edition = 4th}}</ref>

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Also this commentary on some heterocycles "[[Isoquinoline]]s are a class of compounds ([[benzopyridine]]s) which are used in medical contexts (such as the [[anesthetic]] [[dimethisoquin]], the [[antihypertensive]] [[debrisoquine]], and the [[vasodilator]] [[papaverine]]) and in other areas (such as [[disinfectant]] ''N''-laurylisoquinolinium bromide). Isoquinoline itself is efficiently prepared using the [[Pomeranz–Fritsch reaction]], but can also be prepared from benzylamine and [[glyoxal]] [[acetal]] by an analogous approach known as the Schlittler-Müller modification to the Pomeranz–Fritsch reaction. This modification can also be used for preparing substituted isoquinolines.<ref>{{cite book|last = Li|first = J. J.|title = Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications|year = 2014|chapter = Schlittler–Müller modification|publisher = [[Springer Science+Business Media|Springer]]|isbn = 9783319039794|pages = 492|edition = 5th|url = https://books.google.com/books?id=HoXBBAAAQBAJ&q=Name+reactions:+A+collection+of+detailed+reaction+mechanisms}}</ref>" --Smokefoot (talk) 20:44, 26 August 2024 (UTC)