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REFPROP

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From Wikipedia, the free encyclopedia
REFPROP
DeveloperNational Institute of Standards and Technology (NIST)
Release1989; 37 years ago (1989)
Stable release
10.0 / 2018
Written inFortran
Platformx86-64
Available inEnglish
TypeThermophysical property software
LicenseProprietary
Websitewww.nist.gov/srd/refprop

REFPROP is a software program for the prediction of thermophysical properties of fluids, developed by the National Institute of Standards and Technology (NIST).[1][2][3]

The primary component of REFPROP is an equation of state for each implemented fluid. For most pure fluids, the equation of state is obtained by fitting an expression for the Helmholtz free energy to experimental data. This formulation allows the computation of all equilibrium properties of the fluid, such as density, temperature, pressure, sound speed, heat capacity, second virial coefficients, vapor pressures, saturated liquid and vapor densities, enthalpy of vaporization, entropy, and the Joule-Thomson coefficient.[1]

REFPROP also predicts surface tension, viscosity, and thermal conductivity for many fluids, either using extended corresponding states formulations or fluid-specific equations fit directly to experimental data.

Various methods are used to compute the analogous properties of fluid mixtures.

The full list of fluids properties implemented in REFPROP v10.0 can be found in Table 2 of Huber, et al. (2022).[1]

List of implemented fluids

[edit]

REFPROP v10.0 implements equation of state models for 147 pure fluids, listed in Table 1.[1] Except for F3N, R-13, R-123, and R-152a, all of these are Helmholtz free energy formulations.

REFPROP v10.0 also predicts surface tension, viscosity, and thermal conductivity for most of the listed fluids.

Table 1: List of pure fluids implemented in REFPROP v10.0
Short nameFull nameShort formulaCAS number
1,3-ButadieneButa-1,3-dieneC4H6106-99-0
1-ButyneBut-1-yneC4H6107-00-6
1-PentenePent-1-eneC5H10109-67-1
2,2-Dimethylbutane2,2-DimethylbutaneC6H1475-83-2
2,3-Dimethylbutane2,3-DimethylbutaneC6H1479-29-8
3-Methylpentane3-MethylpentaneC6H1496-14-0
AcetonePropanoneC3H6O67-64-1
AcetyleneEthyneC2H274-86-2
AmmoniaAmmoniaNH37664-41-7
ArgonArgonAr7440-37-1
BenzeneBenzeneC6H671-43-2
Butanen-ButaneC4H10106-97-8
Butene1-ButeneC4H8106-98-9
Carbon dioxideCarbon dioxideCO2124-38-9
Carbon monoxideCarbon monoxideCO630-08-0
Carbonyl sulfideCarbon oxide sulfideCOS463-58-1
ChlorineChlorineCl27782-50-5
ChlorobenzeneChlorobenzeneC6H5Cl108-90-7
cis-Butenecis-2-ButeneC4H8590-18-1
Cyclobutene1-CyclobuteneC4H6822-35-5
CyclohexaneCyclohexaneC6H12110-82-7
CyclopentaneCyclopentaneC5H10287-92-3
CyclopropaneCyclopropaneC3H675-19-4
D4OctamethylcyclotetrasiloxaneC8H24O4Si4556-67-2
D5DecamethylcyclopentasiloxaneC10H30O5Si5541-02-6
D6DodecamethylcyclohexasiloxaneC12H36O6Si6540-97-6
DEA2,2'-IminodiethanolC4H11NO2111-42-2
DecaneDecaneC10H22124-18-5
DeuteriumDeuteriumD27782-39-0
Dichloroethane1,2-DichloroethaneC2H4Cl2107-06-2
Diethyl etherDiethyl etherC4H10O60-29-7
Dimethyl carbonateDimethyl ester carbonic acidC3H6O3616-38-6
DimethyletherMethoxymethaneC2H6O115-10-6
DocosaneDocosaneC22H46629-97-0
DodecaneDodecaneC12H26112-40-3
EthaneEthaneC2H674-84-0
EthanolEthyl alcoholC2H6O64-17-5
Ethylene glycol1,2-EthandiolC2H6O2107-21-1
Ethyl benzenePhenylethaneC8H10100-41-4
EthyleneEtheneC2H474-85-1
Ethylene oxideEthylene oxideC2H4O75-21-8
FluorineFluorineF27782-41-4
Heavy waterDeuterium oxideD2O7789-20-0
HeliumHelium-4He7440-59-7
HeptaneHeptaneC7H16142-82-5
HexadecaneHexadecaneC16H34544-76-3
HexaneHexaneC6H14110-54-3
HydrogenHydrogenH21333-74-0
Hydrogen chlorideHydrogen chlorideHCl7647-01-0
Hydrogen sulfideHydrogen sulfideH2S7783-06-4
Isobutane2-MethylpropaneC4H1075-28-5
Isobutene2-Methyl-1-propeneC4H8115-11-7
Isohexane2-MethylpentaneC6H14107-83-5
Isooctane2,2,4-TrimethylpentaneC8H18540-84-1
Isopentane2-MethylbutaneC5H1278-78-4
KryptonKryptonKr7439-90-9
MD2MDecamethyltetrasiloxaneC10H30O3Si4141-62-8
MD3MDodecamethylpentasiloxaneC12H36O4Si5141-63-9
MD4MTetradecamethylhexasiloxaneC14H42O5Si6107-52-8
MDMOctamethyltrisiloxaneC8H24O2Si3107-51-7
MEAEthanolamineC2H7NO141-43-5
MethaneMethaneCH474-82-8
MethanolMethanolCH4O67-56-1
Methyl linoleateMethyl(Z,Z)-9,12-octadecadienateC19H34O2112-63-0
Methyl linolenateMethyl(Z,Z,Z)-9,12,15-octadecatrienoateC19H32O2301-00-8
Methyl oleateMethylcis-9-octadecenoateC19H36O2112-62-9
Methyl palmitateMethyl hexadecanoateC17H34O2112-39-0
Methyl stearateMethyl octadecanoateC19H38O2112-61-8
Methyl cyclohexaneMethylcyclohexaneC7H14108-87-2
MMHexamethyldisiloxaneC6H18OSi2107-46-0
m-Xylene1,3-DimethylbenzeneC8H10108-38-3
NeonNeonNe7440-01-9
Neopentane2,2-DimethylpropaneC5H12463-82-1
NitrogenNitrogenN27727-37-9
Nitrogen trifluorideNitrogen trifluorideF3N7783-54-2
Nitrous oxideDinitrogen monoxideN2O10024-97-2
NonaneNonaneC9H20111-84-2
Novec649,12301,1,1,2,2,4,5,5,5-Nonafluoro-4-(trifluoromethyl)-3-pentanoneC6F12O756-13-8
OctaneOctaneC8H18111-65-9
OrthohydrogenOrthohydrogenH2-
OxygenOxygenO27782-44-7
o-Xylene1,2-DimethylbenzeneC8H1095-47-6
ParahydrogenParahydrogenH2-
PentanePentaneC5H12109-66-0
PerfluorobutaneDecafluorobutaneC4F10355-25-9
PerfluorohexaneTetradecafluorohexaneC6F14355-42-0
PerfluoropentaneDodecafluoropentaneC5F12678-26-2
Propadiene1,2-PropadieneC3H4463-49-0
PropanePropaneC3H874-98-6
Propyl cyclohexanen-Propyl cyclohexaneC9H181678-92-8
PropylenePropeneC3H6115-07-1
Propylene oxide1,2-Epoxy propaneC3H6O75-56-9
PropynePropyneC3H474-99-7
p-Xylene1,4-DimethylbenzeneC8H10106-42-3
R11TrichlorofluoromethaneCCl3F75-69-4
R1123TrifluoroethyleneC2HF3359-11-5
R1131,1,2-Trichloro-1,2,2-trifluoroethaneC2Cl3F376-13-1
R1141,2-DichlorotetrafluoroethaneC2Cl2F476-14-2
R115ChloropentafluoroethaneC2ClF576-15-3
R116HexafluoroethaneC2F676-16-4
R12DichlorodifluoromethaneCCl2F275-71-8
R1216HexafluoropropeneC3F6116-15-4
R1224yd(Z)(Z)-1-Chloro-2,3,3,3-tetrafluoropropeneC3HClF4111512-60-8
R1232,2-Dichloro-1,1,1-trifluoroethaneC2HCl2F3306-83-2
R1233zd(E)trans-1-Chloro-3,3,3-trifluoro-1-propeneC3H2ClF3102687-65-0
R1234yf2,3,3,3-Tetrafluoroprop-1-eneC3F4H2754-12-1
R1234ze(E)trans-1,3,3,3-TetrafluoropropeneC3F4H229118-24-9
R1234ze(Z)cis-1,3,3,3-TetrafluoropropeneC3F4H229118-25-0
R1241-Chloro-1,2,2,2-tetrafluoroethaneC2HClF42837-89-0
R1243zf3,3,3-TrifluoropropeneC3H3F3677-21-4
R125PentafluoroethaneC2HF5354-33-6
R13ChlorotrifluoromethaneCClF375-72-9
R1336mzz(Z)(Z)-1,1,1,4,4,4-Hexafluoro-2-buteneC4H2F6692-49-9
R134a1,1,1,2-TetrafluoroethaneC2H2F4811-97-2
R13I1TrifluoroiodomethaneCF3I2314-97-8
R14TetrafluoromethaneCF475-73-0
R141b1,1-Dichloro-1-fluoroethaneC2H3Cl2F1717-00-6
R142b1-Chloro-1,1-difluoroethaneC2H3ClF275-68-3
R143a1,1,1-TrifluoroethaneC2H3F3420-46-2
R152a1,1-DifluoroethaneC2H4F275-37-6
R161FluoroethaneC2H5F353-36-6
R21DichlorofluoromethaneCHClF75-43-4
R218OctafluoropropaneC3F876-19-7
R22ChlorodifluoromethaneCHClF275-45-6
R227ea1,1,1,2,3,3,3-HeptafluoropropaneC3HF7431-89-0
R23TrifluoromethaneCHF375-46-7
R236ea1,1,1,2,3,3-HexafluoropropaneC3H2F6431-63-0
R236fa1,1,1,3,3,3-HexafluoropropaneC3H2F6690-39-1
R245ca1,1,2,2,3-PentafluoropropaneC3H3F5679-86-7
R245fa1,1,1,3,3-PentafluoropropaneC3H3F5460-73-1
R32DifluoromethaneCH2F275-10-5
R365mfc1,1,1,3,3-PentafluorobutaneC4H5F5406-58-6
R40Methyl chlorideCH3Cl74-87-3
R41FluoromethaneCH3F593-53-3
RC318OctafluorocyclobutaneC4F8115-25-3
RE143aMethyl trifluoromethyl etherC2H3F3O421-14-7
RE245cb2Methyl pentafluoroethyl etherC3H3F5O22410-44-2
RE245fa22,2,2-Trifluoroethyl-difluoromethyl-etherC3H3F5O1885-48-9
RE347mcc(HFE7000)1,1,1,2,2,3,3-Heptafluoro-3methoxypropaneC4H3F7O375-03-1
Sulfur dioxideSulfur dioxideO2S7446-09-5
Sulfur hexafluorideSulfur hexafluorideSF62551-62-4
TolueneMethylbenzeneC7H8108-88-3
trans-Butenetrans-2-ButeneC4H8624-64-6
UndecaneUndecaneC11H241120-21-4
Vinyl chlorideChloroethyleneC2H3Cl75-01-4
WaterWaterH2O7732-18-5
XenonXenonXe7440-63-3

See also

[edit]

References

[edit]
  1. 1 2 3 4 Huber, Marcia L.; Lemmon, Eric W.; Bell, Ian H.; McLinden, Mark O. (2022-10-26). "The NIST REFPROP Database for Highly Accurate Properties of Industrially Important Fluids". Industrial & Engineering Chemistry Research. 61 (42): 15449–15472. doi:10.1021/acs.iecr.2c01427. ISSN 0888-5885. PMC 9619405. PMID 36329835.
  2. ↑ Reynolds, William C.; Colonna, Piero (2018-09-20). Thermodynamics. New York, NY, USA: Cambridge University Press. ISBN 978-0-521-86273-8.
  3. ↑ Penoncello, Steven G. (2018-09-19). Thermal Energy Systems. CRC Press. ISBN 978-1-351-73657-2.
[edit]
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