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formula
system
space group
unit cell Å
volume
density
comment
ref
La3 Cl2 Ge3
monoclinic
C 2/m
a=18.047 b=4.927 c=10.739 β=98.25 Z=4
824.2
5.685
air and water sensitive
[ 1]
formula
system
space group
unit cell Å
volume
density
comment
ref
Br2 Ge3 La3
monoclinic
C 2/m
a =18.622 b =4.3263 c =10.897 β =98° Z=4
869.4
6.069
air and water sensitive
[ 2]
Gd2 GeBr2
trigonal
R 3 m
a = 4.1442, c = 29.487
[ 3]
Gd2 GeBr2
trigonal
P 3 m 1
a = 4.1668, c = 9.8173
semiconductor
[ 3]
formula
system
space group
unit cell Å
volume
density
comment
ref
Y2 GeI2
trigonal
R 3 m
a = 4.2135 c = 31.480 Z=3
484
5.19
bronze
[ 3]
GeI2 La2
trigonal
P 3 m 1
a=4.45 c =10.868 Z=1
186.46
3.381
air and water sensitive
[ 2]
GeI2 La2
trigonal
R 3 m
a=4.465 c =32.591 Z=3
562.7
5.349
air and water sensitive
[ 2]
Ge2 I2 La2
trigonal
P 3 m 1
a =4.272 c =11.8349 Z=1
187.11
6.006
air and water sensitive
[ 2]
GeI3 La3
cubic
I 41 32
a =12.6036 Z=8
2002.1
5.773
air and water sensitive
[ 2]
Ge3 I5 La6
monooclinic
C 2/m
a =19.338 b =4.423 c =14.895, β =128.16° Z=2
1001.7
5.589
air and water sensitive
[ 2]
GeI12 La7
trigonal
R 3
a=16.122 c =10.768 Z=3
2423.8
5.487
air and water sensitive
[ 2]
Gd2 GeI2
trigonal
R 3 m
a = 4.2527 c = 31.657 Z=3
495.84
6.44
bronze
[ 3]
↑ Mattausch, Hansjürgen; Zheng, Chong; Ryazanov, Mikhail; Simon, Arndt (February 2005). "Reduced Lanthanum Halides with Ge as Interstitials: La2I2Ge, La2I2Ge2, La3Cl2Ge3, La3Br2Ge3, La3I3Ge, La6I5Ge3 and La7+xI12Ge" . Zeitschrift für anorganische und allgemeine Chemie (in German). 631 (2– 3): 302– 308. doi :10.1002/zaac.200400269 . ISSN 0044-2313 .
1 2 3 4 5 6 7 Mattausch, Hansjürgen; Zheng, Chong; Ryazanov, Mikhail; Simon, Arndt (February 2005). "Reduced Lanthanum Halides with Ge as Interstitials: La2I2Ge, La2I2Ge2, La3Cl2Ge3, La3Br2Ge3, La3I3Ge, La6I5Ge3 and La7+xI12Ge" . Zeitschrift für anorganische und allgemeine Chemie (in German). 631 (2– 3): 302– 308. doi :10.1002/zaac.200400269 . ISSN 0044-2313 .
1 2 3 4 Lukachuk, Mar'yana; Kremer, Reinhard K.; Mattausch, Hansjürgen; Simon, Arndt (2007-04-01). "New Layered Germanide Halides RE 2 GeX 2 (RE = Y, Gd; X = Br, I)" . Inorganic Chemistry . 46 (8): 3231– 3235. doi :10.1021/ic062425d . ISSN 0020-1669 . PMID 17373789 .
Salts and covalent derivatives of the
germanide ion
GeH4 +H GeH3 −
He
Li
Be
B
C
-N
GeO2
GeF4
Ne
Na
Mg
Al
Si
-P +P
-S
GeCl4 +Cl
Ar
K
Ca
Sc
Ti
V
Cr
MnGe
FeGe
CoGe
Ni
Cu
Zn
Ga
-As +As
-Se
GeBr4 +Br
Kr
Rb
Sr
Y
Zr
Nb
Mo
Tc
Ru
Rh
Pd
Ag
Cd
In
Sn
+Sb
Te
GeI2 GeI4 +I
Xe
Cs
Ba
*
Lu
Hf
Ta
W
Re
Os
Ir
Pt
Au
Hg
Tl
Pb
Bi
Po
At
Rn
Fr
Ra
**
Lr
Rf
Db
Sg
Bh
Hs
Mt
Ds
Rg
Cn
Nh
Fl
Mc
Lv
Ts
Og
*
La
Ce
Pr
Nd
Pm
Sm
Eu?
Gd
Tb
Dy
Ho
Er
Tm?
Yb
**
Ac
Th
Pa
U
Np
Pu
Am
Cm
Bk
Cf
Es
Fm
Md
No
Salts and covalent derivatives of the
iodide ion