// Workers AI · dad joke modeIs Gadolinium acetate attractive? It's got a magnetic personality.
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| Names | |
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| Other names
Gadolinium ethanoate | |
| Identifiers | |
3D model (JSmol) |
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| ChemSpider | |
| ECHA InfoCard | 100.036.534 |
| EC Number |
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PubChem CID |
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CompTox Dashboard (EPA) |
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| Properties | |
| Gd(CH3COO)3 | |
| Appearance | colorless crystal or white powder |
| Density | 1.611 g·cm−3 (tetrahydrate)[1] |
| 0.116 g/mL (tetrahydrate)[1] | |
| Hazards | |
| GHS labelling: | |
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| Warning | |
| H315, H319, H335 | |
| P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Gadolinium acetate is the acetate salt of the lanthanide element gadolinium with the chemical formula Gd(CH3COO)3. It is a colorless crystal that is soluble in water and can form a hydrate.[2] Its tetrahydrate has ground state ferromagnetism.[3]
Preparation
[edit]The tetrahydrate of gadolinium acetate can be crystallized from aqueous solution by reaction of gadolinium oxide and acetic acid:[3]
- Gd2O3 + 6 HOAc + 5 H2O → [(Gd(OAc)3(H2O)2)2]·4H2O
Properties
[edit]The complex [Gd4(CH3COO)4(acac)8(H2O)4] can be obtained by the reflux reaction of gadolinium acetate and acetylacetone in the presence of triethylamine in methanol solution.[4]
References
[edit]- 1 2 Perry, Dale L. (19 April 2016). Handbook of Inorganic Compounds. CRC Press. p. 180. ISBN 978-1-4398-1462-8.
- ↑ Никольский, Б.П., ed. (1971). Справочник химика (in Russian). Vol. 2 (3-е изд., испр ed.). Л.: Химия.
- 1 2 Hatscher, Stephan T.; Urland, Werner (2003). "Unexpected Appearance of Molecular Ferromagnetism in the Ordinary Acetate [Gd(OAc)3(H2O)22]⋅4 H2O". Angewandte Chemie International Edition. 42 (25): 2862–2864. doi:10.1002/anie.200250738. ISSN 1521-3773. PMID 12833342. Archived from the original on 27 May 2020. Retrieved 1 February 2019.
- ↑ Guo, Fu-Sheng; Leng, Ji-Dong; Liu, Jun-Liang; Meng, Zhao-Sha; Tong, Ming-Liang (2 January 2012). "Polynuclear and Polymeric Gadolinium Acetate Derivatives with Large Magnetocaloric Effect". Inorganic Chemistry. 51 (1): 405–413. doi:10.1021/ic2018314. ISSN 0020-1669. PMID 22145780. Retrieved 1 February 2019.