Decay scheme
The decay scheme of a radioactive substance is a graphical presentation of all the transitions occurring in a decay, and of their relationships. Data on decay schemes are extensively measured and tabulated, in various reference tables.[1][2]
The decay scheme is usually plotted in a coordinate system, where the vertical axis is energy, increasing from bottom to top, and the horizontal axis is the proton number, increasing from left to right. The arrows indicate the emitted particles. For the gamma rays (vertical arrows), the gamma energies are given; for the beta decay (oblique arrow), the maximum beta energy. Since energy is conserved and since the particles emitted carry away energy, arrows can only go downward (vertically or at an angle) in a decay scheme.
Examples
[edit]
Cobalt-60
[edit]Consider the cobalt isotope cobalt-60.[3] 60Co decays (with a half-life of 5.272 years) by emitting an electron (beta decay) into an excited state of 60Ni, which then decays very quickly to the ground state of 60Ni, via two gamma decays.
Nickel is to the right of cobalt, since its proton number (28) is higher by one than that of cobalt (27). In beta decay, the proton number increases by one. For a positron decay and also for an alpha decay (see below), the oblique arrow would go from right to left since in these cases, the proton number decreases.
Gold-198
[edit]
A somewhat more complicated scheme is shown here.[4]
198Au can be produced by irradiating natural gold in a nuclear reactor. 198Au decays via beta decay to one of two excited states or to the ground state of the mercury isotope 198Hg. In the figure, mercury is to the right of gold, since the atomic number of gold is 79, that of mercury is 80. The excited states decay after very short times (2.5 and 23 ps) to the ground state.
Metastable
[edit]
While excited nuclear states are usually very short lived, decaying almost immediately after a beta decay, some decay slowly and are called "metastable".
For example, the excited state of the technetium isotope 99mTc (the "m" means it is metastable) decays to the ground state via gamma decay with a half-life of 6 hours.[5]
Alpha decay
[edit]
Polonium-210[6] discovered by Marie Curie, is the penultimate member of the uranium–radium decay series. It decays into a stable lead-isotope with a half-life of 138 days. In almost all cases, the decay is via the emission of an alpha particle of 5.305 MeV. Only in 0.001% of cases, the decay emits an alpha particle of 4.502 MeV, leading to an excited level of 206Pb, which then decays to the ground state via gamma radiation.
Selection rules
[edit]
Alpha- beta- and gamma rays can only be emitted if the conservation laws (energy, angular momentum, parity) are obeyed. This leads to so-called selection rules.
Applications for gamma decay can be found in Multipolarity of gamma radiation. To discuss such a rule in a particular case, it is necessary to know angular momentum and parity for every state. The figure shows the 60Co decay scheme again, with spins and parities given for every state.
References
[edit]- ↑ C.M. Lederer, J.M. Hollander, I. Perlman: Table of Isotopes, Wiley (1968)
- ↑ "NuDat 3". www.nndc.bnl.gov. Retrieved 2026-06-27.
- ↑ K.H.Lieser Einführung in die Kernchemie (1991) S.223, Abb. (7-22); ISBN 3-527-28329-3
- ↑ K.H.Lieser, Nuclear and Radiochemistry (2001), p.61, Fig 5.12; ISBN 3-527-30317-0
- ↑ H.Krieger, Grundlagen der Strahlungsphysik und des Strahlenschutzes (2007), S.117, Fig 3.15; ISBN 978-3-8351-0199-9
- ↑ K.H.Lieser, Nuclear and Radiochemistry (2001), p.52, Fig 5.4; ISBN 3-527-30317-0
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