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// Workers AI · dad joke modeWhy did D-square law go to therapy? It had squared away issues.

From Wikipedia, the free encyclopedia

The d-square law or -law is a relationship between diameter and time for an isolated, spherical droplet when it evaporates quasi-steadily, which was first observed by Boris Sreznevsky in 1882,[1] and was explained by Irving Langmuir in 1918.[2] If and are the droplet diameter and time, then -law pertains to the relation[3][4]

where is the initial time, is the initial droplet diameter and is called the evaporation constant.

Crespo–Liñán correction

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Crespo–Liñán correction refers to a small correction of the order to the d-square law in terms of the small parameter , the ratio of gas to liquid density. Antonio Crespo and Amable Liñán[5] showed that the quasi-steady approximation is correct in the inner zone having the size on the order of droplet diameter, but becomes invalid in an outer zone with a size larger than the droplet diameter by the factor of , where the unsteady terms cannot be neglected.[6]

References

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  1. Sreznevsky, B. I. (1882). About evaporation of liquids. Journal of the Russian Physical Chemistry Society, ZhRFKhO, 14(8).
  2. Langmuir, I. (1918). The evaporation of small spheres. Physical review, 12(5), 368.
  3. Williams, F. A. (2018). Combustion theory. CRC Press. Chapter 3
  4. Liñán, A., & Williams, F. A. (1993). Fundamental aspects of combustion. Oxford university press.
  5. Crespo, A., & Linan, A. (1975). Unsteady effects in droplet evaporation and combustion. Combustion Science and Technology, 11(1-2), 9-18.
  6. Williams, F. A., Nayagam, V., & Dietrich, D. L. (2022). Discussion of likely causes of possible variation of the effective ambient environment during quasi-steady droplet combustion supported by cool-flame chemistry. Combustion and Flame, 239, 111659.