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// Workers AI · dad joke modeWhy did the propargyl group go to therapy? It had an alkyne to work through.

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Chemical structure of the propargyl group.

In organic chemistry, the propargyl group is a functional group of 2-propynyl with the structure HC≡C−CH2. It is an alkynyl group derived from propyne (HC≡C−CH3).

The term propargylic refers to a saturated position (sp3-hybridized) on a molecular framework next to an alkynyl group. The name comes from mix of propene and argentum, which refers to the typical reaction of the terminal alkynes with silver salts.[citation needed]

The term homopropargylic designates in the same manner

  • a saturated position on a molecular framework next to a propargylic group and thus two bonds from an alkyne moiety.[1]
  • a 3-butynyl fragment, HC≡C−CH2CH2, or substituted homologue.

See also

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References

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  1. Ferreira, Franck; Denichoux, Aurélien; Chemla, Fabrice; Bejjani, Joseph (2004). "Highly Diastereoselective Syntheses of Propargylic Acid and Homopropargylic Systems". Synlett (12): 2051–2065. doi:10.1055/s-2004-832816.