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// Workers AI · dad joke modeWhat did Lutetium(III) bromide say? "I'm bonded to you.

From Wikipedia, the free encyclopedia
(Redirected from Lutetium bromide)
Lutetium(III) bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.935 Edit this at Wikidata
EC Number
  • 238-446-5
  • InChI=1S/3BrH.Lu/h3*1H;/q;;;+3/p-3
    Key: DWHGOINJUKABSY-UHFFFAOYSA-K
  • [Lu+3].[Br-].[Br-].[Br-]
Properties
LuBr3
Molar mass 414.68[1]
Appearance White Powder
Density 1.025[2]
Melting point 1,400 °C (2,550 °F; 1,670 K)[2]
Will dissolve[2]
Structure
Rhombohedric FeCl3 like[3]
Thermochemistry
66.9 J/mol K[3]
48.8 kJ/mol[3]
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H315, H319, H335[1]
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501[4]
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth (blue): no hazard codeFlammability 0: Will not burn. E.g. waterInstability (yellow): no hazard codeSpecial hazards (white): no code
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lutetium(III) bromide is an inorganic chemical compound with the formula LuBr3. It exists as a colorless anhydrous solid. From aqueous solution, a hydrated form crystallizes [Lu(H2O)8]Br3.[5]

Properties

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Formation and reactions

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Lutetium(III) bromide can be synthesized through the following reaction:[6]

2 Lu(s) + 3 Br2(g) → 2 LuBr3(s)

If burned, lutetium(III) bromide may produce hydrogen bromide and metal oxide fumes.[7]

Lutetium(III) bromide reacts to strong oxidizing agents.[7]

See also

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References

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  1. 1 2 Elements, American. "Lutetium Bromide". American Elements. Retrieved 22 December 2016.
  2. 1 2 3 Phillips, Sidney L.; Perry, Dale L. (1995). Handbook of inorganic compounds. Boca Raton: CRC Press. p. 232. ISBN 9780849386718.
  3. 1 2 3 L., Rycerz; M., Gaune-Escard (2008). "Lanthanide(III) halides: Thermodynamic properties and their correlation with crystal structure". Journal of Alloys and Compounds. 450 (1–2): 167–174. doi:10.1016/j.jallcom.2006.12.096. Retrieved 22 December 2016.
  4. "Lutetium bromide | Br3Lu - PubChem". pubchem.ncbi.nlm.nih.gov. Retrieved 22 December 2016.
  5. Semenova, Lioubov I.; Junk, Peter C.; Skelton, Brian W.; White, Allan H. (1999). "Structural Systematics of Rare Earth Complexes. XVI ('Maximally') Hydrated Rare Earth( III ) Bromides". Australian Journal of Chemistry. 52 (6): 531–538. doi:10.1071/CH98047.
  6. Winter, Mark. "Lutetium»reactions of elements [WebElements Periodic Table]". www.webelements.com. Retrieved 22 December 2016.
  7. 1 2 "Lutetian bromide" (PDF). SDS. Retrieved 22 December 2016.