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// Workers AI · dad joke modeWhy did Dysprosium(III) nitrate go to therapy? It had a negative bond.

From Wikipedia, the free encyclopedia
(Redirected from Dysprosium nitrate)
Dysprosium(III) nitrate
Names
Other names
Dysprosium nitrate, Dysprosium trinitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.360 Edit this at Wikidata
EC Number
  • 233-410-5
  • pentahydrate: 629-564-1
  • InChI=1S/Dy.3NO3/c;3*2-1(3)4/q+3;3*-1
    Key: DVENVBCPDCQQGD-UHFFFAOYSA-N
  • monhydrate: InChI=1S/Dy.3NO3.H2O/c;3*2-1(3)4;/h;;;;1H2/q+3;3*-1;
    Key: DSEBQRTVZFLVND-UHFFFAOYSA-N
  • pentahydrate: InChI=1S/Dy.3NO3.5H2O/c;3*2-1(3)4;;;;;/h;;;;5*1H2/q+3;3*-1;;;;;
    Key: NOTQUFQJAWMLCE-UHFFFAOYSA-N
  • hexahydrate: InChI=1S/Dy.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;
    Key: DCKWZDOAGNMKMX-UHFFFAOYSA-N
  • O.[Dy+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
  • monhydrate: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.[Dy+3]
  • pentahydrate: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.[Dy+3]
  • hexahydrate: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Dy+3]
Properties
Dy(NO3)3
Molar mass 348.51
Appearance Yellowish crystals
Melting point 88.6[1] °C (191.5 °F; 361.8 K)
Soluble
Hazards
GHS labelling:
GHS03: OxidizingGHS07: Exclamation mark
Warning
H272, H315, H319, H335
P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
Related compounds
Related compounds
Terbium(III) nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dysprosium(III) nitrate is an inorganic compound, a salt of dysprosium and nitric acid with the chemical formula Dy(NO3)3. The compound forms yellowish crystals, dissolves in water, forms a crystalline hydrate.[2]

Synthesis

[edit]

Anhydrous salt is obtained by the action of nitrogen dioxide on dysprosium(III) oxide:[3]

The action of nitrogen dioxide on metallic dysprosium:

Physical properties

[edit]

Dysprosium(III) nitrate forms yellowish crystals.[4]

The anhydrous nitrate forms a crystalline hydrate in wet air with the ideal composition of Dy(NO3)3·5H2O, which melts in its own crystallization water at 88.6 °C.[5][6]

All hydrates (anhydrous, pentahydrate, and hexahydrate) are soluble in water and ethanol, hygroscopic.

Chemical properties

[edit]

Hydrated dysprosium nitrate thermally decomposes to form DyONO3,[citation needed] and further heating produces dysprosium oxide.

Application

[edit]

Dysprosium(III) nitrate is used as a catalyst.

References

[edit]
  1. "Dysprosium(III) nitrate | CAS 10031-49-9". scbt.com. Retrieved 18 August 2021.
  2. Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3117. ISBN 978-0-412-30120-9. Retrieved 18 August 2021.
  3. Edelmann, Frank T.; Herrmann, Wolfgang A. (14 May 2014). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 6, 1997: Volume 6: Lanthanides and Actinides. Georg Thieme Verlag. p. 23. ISBN 978-3-13-179221-1. Retrieved 18 August 2021.
  4. "Dysprosium(III) nitrate - Hazardous Agents | Haz-Map". haz-map.com. Retrieved 18 August 2021.
  5. "Dysprosium(III) nitrate hydrate". Sigma Aldrich. Retrieved 18 August 2021.
  6. "10031-49-9 - Dysprosium(III) nitrate pentahydrate, 99.9% (REO) - 12922 - Alfa Aesar". Alfa Aesar. Retrieved 18 August 2021.