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// Workers AI · dad joke modeWhat did antimony germanides say? "We bond well.

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From Wikipedia, the free encyclopedia
(Redirected from Antimonide germanide)

Antimony germanides or antimonide germanides are compounds containing germanium and antimony along with one or more metals. Bonding is only partially ionic, and can be considered as a Zintl phase, rather than antimonide ions with germanide ions. There are often covalent bonds between the antimony, reducing its apparent valence.[1][2]

Some of the compounds have varying ratios of antimony and germanium. For example at 600 °C Gd5Sb3 and Gd5Ge3 can form a solid solution.[3]

Gold does not form a ternary compound,[4] and neither does gallium[5] or bismuth.[6]

Germanium containing antimonides have been investigated for use in thermoelectric materials.[7]

Production

[edit]

Antimonide germanide compounds can be made by heating a mixture of the powdered elements together at 600° or higher. Tantalum is used as the crucible material, as it does not react. Oxygen must be excluded to stop oxides from forming.[3]

[edit]

Related compounds include substitution of germanium with other elements from group 13 or 14: SiSb, SnSb, PbSb, AlSb, GaSb, and InSb. Replacing antimony with other pnictides can form related compounds such as phosphidosilicates, arsenidosilicates, phosphidogermanates, arsenidogermanates, phosphidostannates, arsenidostannates, phosphidoplumbates, and arsenidoplumbates.[1]

List

[edit]
formula system space group unit cell volume density comment ref
TiGeSb tetragonal P4/nmm a = 3.7022 c = 8.214 Z = 2 112.58 [8]
Fe3Ge2Sb hexagonal P6/mmm a = 8.9070 c = 7.9217 [9]
FeGe1−𝑥⁢Sb𝑥 x<0.05 hexagonal P6/mmm [10]
FeGe1−𝑥⁢Sb𝑥 0.1<x<0.2 hexagonal P63/mmm [10]
Ti0.5Fe6Ge5Sb hexagonal P6/mmm a=8.845 c=7.9785 Z=3 [11]
Cr0.8Fe5.3Ge5.2Sb0.8 hexagonal P6/mmm a=8.850 c=8.025 Z=3 [11]
Mn1.8Fe4.6Ge4.9Sb1.1 hexagonal P6/mmm a=8.910 c=7.9665 Z=3 [11]
CoGexSb1-x hexagonal P63/mmm Ge and Sb disordered [12]
Co3Ge2Sb hexagonal P6/mmm a = 8.913 c = 7.6312 Z = 6 [12]
Cu6GeSb hexagonal P63/mmc a=4.16, c=7.47 [13][14]
Ge2GaSb cubic gallium antimonide and germanium forma solid solution [15]
Y5Sb2Ge2 [16]
ZrGeSb [17]
ZrGe0.211Sb1.78 orthorhombic Pnma a = 7.304 b = 3.9513 c = 9.576 Z=4 276.35 7.763 [18]
NbGeSb tetragonal P4/nmm a=3.75 c=8.30 [19]
ZnIn18GeSb20 [7]
La5Ge3Sb hexagonal P63/mcm a=9.156 c=7.231 Z=2 525.0 [20]
La6Ge2.8Sb13.2 orthorhombic Immm a = 4.3034 b = 10.851 c = 27.073 Z=2 1272.6 Metallic; columns of trigonal prisms [21][22]
La12Ge6.6Sb21 orthorhombic Immm a=4.3165 b=15.205 c=34.443 Z=2 [23]
Ce2GeSb3 orthorhombic Cmmm Sb ZigZag chain [24][1]
Ce3GeSb [24]
Ce5Ge3Sb2 [24]
Ce6Ge5Sb12 orthorhombic Immm a=4.2972 b=10.740 c=26.791 Z=2 1236.4 Metallic; columns of trigonal prisms [21]
Ce12Ge5.2Sb26.8 C222 a=8.6075 b=21.5154 c=26.8227 4967.4 7.117 [25]
Pr6Ge5Sb12 orthorhombic Immm a=4.2574 b=10.677 c=26.626 Z=2 1213.1 Metallic; columns of trigonal prisms [21]
Pr12Ge6.48Sb21 orthorhombic Immm a=4.2578 b=114.9777 c=33.938 Z=2 2164.3 7.240 [23]
Nd6Ge3.61Sb12.4 orthorhombic Immm a = 4.2310 b = 10.6362 c = 26.526 Z=2 1197.8 Metallic; columns of trigonal prisms [21][22]
Sm6Ge5Sb12 orthorhombic Immm a=4.1932 b=10.537 c=26.350 Z=2 1164.5 Metallic; columns of trigonal prisms [21]
Gd4Ge1.97Sb1.03 cubic I43d a=9.0111 [26]
Gd5Ge0.9Sb3.1 orthorhombic Cmce a = 12.241, b = 8.025, c = 8.039 Z=4 8.539 light grey [3]
Gd2Ge3.28Sb0.65 orthorhombic Cmcm a = 4.0198, b = 30.373, c = 4.1340 Z=4 8.440 grey [3]
Gd6Ge4.3Sb11.7 orthorhombic Immm a = 4.1509 b = 10.4438 c = 26.2400 Z=2 1136.7 Metallic; columns of trigonal prisms [21][22]
Gd8Ge13.29Sb1.72 orthorhombic Cmcm a = 4.02832 b =30.4101 c = 4.14426 Z=1 507.68 7.953 [26]
Gd1.02 Sc0.98Ge0.9Sb0.1 tetragonal I4/mmm a=4.2730 c=15.658 ferromagnetic < 333K [27]
Gd1.02 Sc0.98Ge0.5Sb0.5 tetragonal I4/mmm a=4.3277 c=15.904 ferromagnetic < 170K [27]
Gd1.02 Sc0.98Ge0.2Sb0.8 tetragonal P4/nmm a=4.3192 c=8.1461 [27]
Tb6Ge5Sb12 orthorhombic Immm a=4.1305 b=10.393 c=26.139 Z=2 1122.1 Metallic; columns of trigonal prisms [21]
Dy6Ge5Sb12 orthorhombic Immm a=4.103 b=10.345 c=26.014 Z=2 1104.2 Metallic; columns of trigonal prisms [21]
Dy5Sb2Ge2 orthorhombic Cmca [16]
Ho5Sb2Ge2 orthorhombic Cmca [16]
Er5Sb2Ge2 orthorhombic Cmca [16]
Tm5Sb2Ge2 orthorhombic Cmca [16]
Yb8Ge3Sb5 tetragonal I4/mmm a=15.8965 c=6.8206 Z=4 1723.6 8.520 metallic silver; 1∞(Ge3)4-; negative thermal expansion under 15 K [28][29][30]
CaYb4Al2Sb5.8Ge0.2 orthorhombic [2]
CaYb4Al2Sb5.5Ge0.5 orthorhombic P1m1 a=13.9770 b=4.4203 c=11.9985 741.30 [2]
CaYb4Al2Sb5.3Ge0.7 orthorhombic [2]
HfGe0.205Sb1.795 orthorhombic Pnma a=7.312 b=3.943 c=9.488 Z=4 273.5 10.002 [18]
Hf3Cu2Ge3.58Sb1.42 tetragonal P4/nmm a = 3.8023 c = 24.575 Z=2 355.3 10.241 [31]

References

[edit]
  1. 1 2 3 Mills, A (1 November 2002). "Chains, planes, and antimonides". Coordination Chemistry Reviews. 233–234: 207–222. doi:10.1016/S0010-8545(02)00097-8.
  2. 1 2 3 4 Lim, Sung-Ji; Nam, Gnu; Shin, Seungeun; Ahn, Kyunghan; Lee, Yunho; You, Tae-Soo (6 May 2019). "Anionic Doping and Cationic Site Preference in CaYb 4 Al 2 Sb 6– x Ge x ( x = 0.2, 0.5, 0.7): Origin of the Enhanced Seebeck Coefficient and the Structural Transformation". Inorganic Chemistry. 58 (9): 5827–5836. doi:10.1021/acs.inorgchem.9b00181. PMID 30985118.
  3. 1 2 3 4 Department of Inorganic Chemistry, Ivan Franko National University of Lviv; Dankevych, Roman; Tokaychuk, Yaroslav; Department of Inorganic Chemistry, Ivan Franko National University of Lviv (2022). "The ternary system Gd–Ge–Sb at 600°C" (PDF). Chemistry of Metals and Alloys. 15 (1/2): 12–16. doi:10.30970/cma15.0423.
  4. ↑ Wang, J.; Leinenbach, C.; Roth, M. (October 2009). "Thermodynamic description of the Au–Ge–Sb ternary system". Journal of Alloys and Compounds. 485 (1–2): 577–582. doi:10.1016/j.jallcom.2009.06.030.
  5. ↑ Manasijević, Dragan; Minić, Duško; Balanović, Ljubiša; Premović, Milena; Gorgievski, Milan (February 2019). "Experimental Investigation and Thermodynamic Extrapolation of the Ga-Ge-Sb Phase Diagram". Journal of Phase Equilibria and Diffusion. 40 (1): 34–44. Bibcode:2019JPED...40...34M. doi:10.1007/s11669-018-0685-5.
  6. ↑ Premović, Milena; Minić, Duško; Ćosović, Vladan; Manasijević, Dragan; Živković, Dragana (October 2014). "Experimental Investigation and Thermodynamic Calculations of the Bi-Ge-Sb Phase Diagram". Metallurgical and Materials Transactions A. 45 (11): 4829–4841. Bibcode:2014MMTA...45.4829P. doi:10.1007/s11661-014-2445-4.
  7. 1 2 Kim, Donghun; Kurosaki, Ken; Ohishi, Yuji; Muta, Hiroaki; Yamanaka, Shinsuke (2012). "Reduction in Lattice Thermal Conductivity of InSb by Formation of the ZnIn18GeSb20 Alloy". Materials Transactions. 53 (11): 1976–1980. doi:10.2320/matertrans.M2012176. ISSN 1345-9678.
  8. ↑ Lam, Robert; Mar, Arthur (15 September 2009). "Titanium germanium antimonide, TiGeSb". Acta Crystallographica Section E: Structure Reports Online. 65 (9): i68. doi:10.1107/S1600536809031559. PMC 2969891. PMID 21577387.
  9. ↑ Gibson, Quinn D.; Daou, Ramzy; Zanella, Marco; Alaria, Jonathan; Rosseinsky, Matthew J. (2023-07-05). "Magnetic, electronic, and thermal properties of buckled kagome Fe 3 Ge 2 Sb". Physical Review B. 108 (3) 035102. doi:10.1103/PhysRevB.108.035102. ISSN 2469-9950.
  10. 1 2 Huang, Jiale; Shang, Chenglin; Qin, Jianfei; Pan, Feihao; Shi, Bingxian; Wang, Jinchen; Liu, Juanjuan; Xu, Daye; Zhang, Hongxia; Wang, Hongliang; Hao, Lijie; Bao, Wei; Cheng, Peng (2023-11-28). "FeGe 1 − x Sb x : A series of kagome metals with noncollinear antiferromagnetism". Physical Review B. 108 (18) 184431. doi:10.1103/PhysRevB.108.184431. hdl:2031/98d09f5c-e3ec-492e-a886-b966488b1724. ISSN 2469-9950.
  11. 1 2 3 Mills, Allison M.; Anderson, Erica J.; Mar, Arthur (June 2001). "Structures of the quaternary iron germanium antimonides R1−x(R,Fe)6Ge4(Ge,Sb)2 (R=Ti, Cr, Mn), filled derivatives of FeGe1−xSbx". Journal of Alloys and Compounds. 322 (1–2): 103–112. doi:10.1016/S0925-8388(01)01020-9.
  12. 1 2 Mills, Allison M; Lam, Robert; Mar, Arthur (1998-11-01). "Ternary cobalt germanium pnictides CoGe x Pn 1- x ( Pn = P, As, Sb) and the structure of Co 3 Ge 2 Sb, an intermetallic compound with stuffed Sb 2 pairs". Canadian Journal of Chemistry. 76 (11): 1588–1594. doi:10.1139/v98-142. ISSN 0008-4042.
  13. ↑ Premović, Milena; Du, Yong; Minić, Duško; Zhang, Cong; Manasijević, Dragan; Balanović, Ljubiša; Marković, Ivana (December 2017). "Experimental investigation and thermodynamic calculation of the Cu-Ge-Sb system". Journal of Alloys and Compounds. 726: 820–832. doi:10.1016/j.jallcom.2017.08.051.
  14. ↑ Lenz, Jürgen; Schubert, Konrad (1971-11-01). "Über einige Leerstellen- und Stapelvarianten der Beta-Messing Strukturfamilie". International Journal of Materials Research. 62 (11): 810–816. Bibcode:1971IJMR...62..810L. doi:10.1515/ijmr-1971-621110. ISSN 2195-8556.
  15. ↑ DUWEZ, POL; WILLENS, R. H.; KLEMENT, JR, W. (14 June 1960). "Metastable Solid Solutions in the Gallium Antimonide-Germanium Pseudo-binary System" (PDF). Journal of Applied Physics. 31 (8): 1500. Bibcode:1960JAP....31.1500D. doi:10.1063/1.1735872. Archived from the original (PDF) on 2017-09-22.
  16. 1 2 3 4 5 Kozlov, A.Yu.; Pavlyuk, V.V.; Davydov, V.M. (February 2004). "The crystal structure of the new ternary compounds RE5Sb2X2 (RE—Y, Tb, Dy, Ho, Er, Tm; X—Si or Ge)". Intermetallics. 12 (2): 151–155. doi:10.1016/j.intermet.2003.09.010.
  17. ↑ Ozyar, U.F.; Deligoz, E.; Colakoglu, K. (February 2015). "Systematic study on the anisotropic elastic properties of tetragonal XYSb (X = Ti, Zr, Hf; Y = Si, Ge) compounds". Solid State Sciences. 40: 92–100. Bibcode:2015SSSci..40...92O. doi:10.1016/j.solidstatesciences.2015.01.001.
  18. 1 2 Soheilnia, Navid; Assoud, Abdeljalil; Kleinke, Holger (2003-11-01). "MA δ Sb 2- δ (M = Zr, Hf; A = Si, Ge): A New Series of Ternary Antimonides and Not "β-ZrSb 2 "". Inorganic Chemistry. 42 (22): 7319–7325. doi:10.1021/ic0347440. ISSN 0020-1669. PMID 14577804.
  19. ↑ Guo, Lei; Zhao, Weiyao; Ding, Ning; Shi, Xin-Yao; Xu, Meng; Chen, Lei; Gao, Guan-Yin; Dong, Shuai; Zheng, Ren-Kui (2020-10-14). "Magnetotransport properties of square-net compounds of NbSiSb and NbGeSb single crystals". Journal of Physics: Condensed Matter. 32 (43): 435701. arXiv:2007.15437. Bibcode:2020JPCM...32Q5701G. doi:10.1088/1361-648X/aba385. ISSN 0953-8984. PMID 32634789.
  20. ↑ Guloy, Arnold M.; Corbett, John D. (August 1993). "The lanthanum-germanium system. Nineteen isostructural interstitial compounds of the La5Ge3 host". Inorganic Chemistry. 32 (16): 3532–3540. doi:10.1021/ic00068a025. ISSN 0020-1669.
  21. 1 2 3 4 5 6 7 8 Deakin, Laura; Lam, Robert; Mar, Arthur (2001-02-01). "Rare-Earth Germanium Antimonides RE 6 Ge 5 - x Sb 11+ x ( RE = La−Nd, Sm, Gd−Dy). II. Magnetic and Transport Properties". Inorganic Chemistry. 40 (5): 960–965. doi:10.1021/ic0014078. ISSN 0020-1669.
  22. 1 2 3 Lam, Robert; McDonald, Robert; Mar, Arthur (2001-02-01). "Rare-Earth Germanium Antimonides RE 6 Ge 5 - x Sb 11+ x ( RE = La−Nd, Sm, Gd−Dy). I. Syntheses and Structures". Inorganic Chemistry. 40 (5): 952–959. doi:10.1021/ic0009472. ISSN 0020-1669.
  23. 1 2 Bie, Haiying; Mar, Arthur (September 2009). "Ge Pairs and Sb Ribbons in Rare-Earth Germanium Antimonides RE 12 Ge 7− x Sb 21 ( RE =La–Pr)". Chemistry – an Asian Journal. 4 (9): 1465–1473. doi:10.1002/asia.200900063. ISSN 1861-4728. PMID 19554602.
  24. 1 2 3 Stetskiv, A.O.; Pavlyuk, V.V.; Bodak, O.I. (May 1998). "Interaction of the Components in the Ce-Ge-Sb System". Polish Journal of Chemistry. 72 (5): 956–958.
  25. ↑ Nasir, Navida; Grytsiv, Andriy; Rogl, Peter; Saccone, Adriana; Giester, Gerald (April 2009). "Phase equilibria in systems Ce–M–Sb (M=Si, Ge, Sn) and superstructure Ce12Ge9−xSb23+x (x=3.8±0.1)". Journal of Solid State Chemistry. 182 (4): 645–656. doi:10.1016/j.jssc.2008.12.009.
  26. 1 2 Liu, Hongrui; Liao, Changzhong; Zeng, Weijing; Yang, Tonghan; Zeng, Lingmin; He, Wei (June 2020). "Phase equilibria in the Gd-Ge-Sb system at 773 K and the magnetic properties of novel compound Gd8Ge13.29Sb1.72". Journal of Alloys and Compounds. 825 153841. doi:10.1016/j.jallcom.2020.153841.
  27. 1 2 3 Guillou, F; Pathak, A K; Hackett, T A; Paudyal, D; Mudryk, Y; Pecharsky, V K (2017-12-06). "Crystal, magnetic, calorimetric and electronic structure investigation of GdScGe 1– x Sb x compounds". Journal of Physics: Condensed Matter. 29 (48): 485802. doi:10.1088/1361-648X/aa93aa. ISSN 0953-8984. OSTI 1411177. PMID 29120868.
  28. ↑ Salvador, James R.; Bilc, Daniel; Mahanti, S. D.; Hogan, Tim; Guo, Fu; Kanatzidis, Mercouri G. (2004-04-01). "Yb 8 Ge 3 Sb 5 , a Metallic Mixed-Valent Zintl Phase Containing the Polymeric 1 ∞ [Ge 3 4- ] Anions". Journal of the American Chemical Society. 126 (14): 4474–4475. Bibcode:2004JAChS.126.4474S. doi:10.1021/ja0395487. ISSN 0002-7863. PMID 15070338.
  29. ↑ Margadonna, Serena; Prassides, Kosmas; Chondroudi, Maria; Salvador, James R.; Kanatzidis, Mercouri G. (2005). "Temperature-induced abrupt volume inflation in the mixed-valence ternary Zintl phase Yb8Ge3Sb5". Chemical Communications (46): 5754–5756. doi:10.1039/b511606f. ISSN 1359-7345. PMID 16307135.
  30. ↑ Kosaka, Masashi; Kasuya, Shunsuke; Michimura, Shinji; Iizuka, Ryosuke; Uwatoko, Yoshiya (2020-03-19). "Magnetic and Transport Properties of Rare Earth Zintl Compound Yb8Ge3Sb5". Proceedings of the International Conference on Strongly Correlated Electron Systems (SCES2019). Physical Society of Japan. doi:10.7566/JPSCP.30.011138. ISBN 978-4-89027-142-9.
  31. ↑ Guch, Mykhailo; Sankar, Cheriyedath Raj; Assoud, Abdeljalil; Kleinke, Holger (2010-12-14). "Crystal Structure and Physical Properties of the New Antimonide Hf 3 Cu 2 Ge 3.58 Sb 1.42". Chemistry of Materials. 22 (23): 6433–6437. doi:10.1021/cm102632a. ISSN 0897-4756.
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